Q. 47. In a buffer solution containing equal concentration  of 
 and HB, the 
 . The pH of buffer solution  is:
Sol.

            For the buffer solution  containing equal concentration of 
 and HB
            
            
Answer: (4)
Q. 48. AB crystallizes in a body centred cubic lattice with edge length 'a' equal to 387 pm. The distance between two oppositively charged ions in the lattice is:
Sol:
For BCC lattice body diagonal is equal to a 
 
   The  distance between the two oppositely charged ions = 
                                                                                    = 
       
            Answer :  (1)
Q. 49. The existence of two different coloured complexes  with the composition of
            
Sol.

Answer : (2)
Q. 50. Among the given compounds, the most susceptible to nucleophilic attack at the carbonyl group is:




Sol:
 is the weakest base  and hence better leaving group
Answer :  (4)