Q. 21. Which of the following compounds has the lowest melting point?
(1) CaF2 (2) CaCl2
(3) CaBr2 (4) CaI2
Sol:
CaI2 has lowest melting point
Answer : (4)
Q. 22. Which of the following pairs of metals is purified by van Arkel method?
(1) Ni and Fe (2) Ga and In
(3) Zr and Ti (4) Ag and Au
Sol .
Zr and Ti are purified by van Arkel method
Answer : (3)
Q. 23. The correct order of increasing bond length of C – H, C – O, C – C and C = C is
(1) C -H < C - O < C - C < C = C
(2) C -H < C = C < C -O < C - C
(3) C -C < C = C < C - O < C -H
(4) C -O < C - H < C - C < C = C
Sol.
Fact
Answer : (2)
Q. 24. Acidified K2Cr2O7 solution turns green when Na2SO3 is added to it. This is due to the formation of
(1) CrSO4 (2) Cr2(SO4)3
(3) (4) Cr2(SO3)3
Sol.
Answer : (2)
Q. 25. For the four successive transition elements (Cr, Mn, Fe and Co), the stability of + 2 oxidation state will be there in which of the following order?
(1) Cr > Mn > Co > Fe (2) Mn > Fe > Cr > Co
(3) Fe > Mn > Co > Cr (4) Co > Mn > Fe > Cr
(At. nos. Cr = 24, Mn = 25, Fe = 26, Co = 27)
Sol.
On the basis of electrode potentials, the correct order is Mn > Fe > Cr > Co
Answer : (2)